화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2022년 봄 (05/11 ~ 05/13, 제주국제컨벤션센터(ICC JEJU))
권호 26권 1호
발표분야 포스터-고분자
제목 Enhancing the through-plane thermal conductivity of a cellulose nanofiber film via nitride surface functionalization and cellulose chemical crosslinking
초록 CNF-BN hybrid filler consist of cellulosenanofiber and boron nitride was fabricated by ball milling exfoliation method with the introduction of oxalic acid to provide hydroxyl groups which make better compatibility between CNF and BN via hydrogen bonding.After functionalization and CNF grafting, the filler was well dispersed intothe CNF matrix with tetraethyl orthosilicate for chemical crosslinking.c-CNF-BN/CNF film was then fabricated by vacuum infiltration. The voids and defects of the film surface decreased due to the tangled cellulose nanofiber withthe help of crosslink agent, It helps the construction of efficient heat pathway. As a result, the through-plane thermal conductivity increased from 0.5W m-1 K-1 to 1.69W m-1 K-1​ with 37.5vol% BN loading. Hence, the c-CNF-BN/CNFfilm can be used as the composite for efficient thermal management for displays of electronic device.



저자 양원영, 조영성, 김주헌
소속 중앙대
키워드 Thermal conductivity; chemical crosslinking; cellulose nanofiber; surface functionalization
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