화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2017년 가을 (11/08 ~ 11/10, 부산 벡스코(BEXCO))
권호 21권 2호
발표분야 환경에너지_포스터
제목 Porous structured potassium ferric hexacyanoferrate-alginate/clay hydrogel for selective and rapid cesium adsorption
초록 Radioactive contaminant adsorbents require well-designed morphologies for effective interaction with radioactive species selectively and high structural stability during adsorption. Herein, we demonstrate a pomegranate-like micro-scavenger cage (P-MSC) with high adsorption capacity towards radioactive cesium (137Cs). The resulting micro-scavenger cage shows enhancing properties compared to alginate bead gelled by traditional methods using Ca2+. The proton-exchange between cesium and P-MSC result in rapid adsorption, within 10 min, with a high removal capacity. The resulting P-MSC has a 236-fold higher distribution coefficient toward cesium than traditional Ca-alginate bead. The maximum cesium removal capacity of the P-MSC is 108.06 mg/g. It is found that the P-MSC have a removal efficiency of 99.24% for radioactive cesium, showing that the material holds great promise for the clean-up of radioactive cesium contaminated seawater around nuclear plants and/or after nuclear accidents.
저자 허윤석1, 장성찬1, 강성민1, 이일송1, 노창현2
소속 1인하대, 2한국원자력(연)
키워드 alginate; clay; cesium; adsorption; potassium ferric hexacyanoferrate
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