화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2014년 봄 (04/23 ~ 04/25, 창원컨벤션센터)
권호 20권 1호, p.557
발표분야 에너지
제목 New and novel graphene- polyethylene oxide composite solid electrolyte for solid state dye sensitized solar cells
초록 In this work, the effective composite electrolytes were prepared by the mixing the graphene (Gr) and polyethylene oxide (PEO) for the fabrication of solid electrolyte of dye sensitized solar cells (DSSCs). Morphological characterization revealed that Gr sheets were uniformly coated by the PEO layer through the ester carboxylate bonding. The Gr-PEO composite electrolyte exhibited the enhanced generation of iodide ions in redox couple. From conductivity properties, Gr-PEO composite electrolyte with 0.5 wt% Gr presented a higher ionic conductivity (3.32 mS.cm-1) than those of PEO and other composite electrolytes at room temperature. A high overall conversion efficiency (~ 5.23%) with very high short circuit current (JSC) of 18.32 mA/cm2, open circuit voltage (VOC) of 0.592 V and fill factor (FF) of 0.48 was achieved in DSSCs fabricated with Gr-PEO composite electrolyte.
저자 이진우1, M. Shaheer Akhtar2, 양오봉3
소속 1전북대, 2School of semiconductor and Chemical Engineering, 3Solar Energy Research Center
키워드 graphene; polyethylene oxide; electrolyte
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