화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2015년 봄 (04/08 ~ 04/10, 대전컨벤션센터)
권호 40권 1호
발표분야 Self-Assembled Materials
제목 Self-assembly of surface structure of B4 liquid crystal in nano-confined geometry
초록 The liquid crystal (LC) structure undergoes structural transition as changing the LC film thickness due to the change of boundary conditions felt by LC molecules. Here, we hexagonally generated the individual surface structures of B4 LC phase by simply utilizing the nano-confined geometry. Formation of surface structures was morphologically evolved from individually confined barrel-like structures to hexagonal knit-like estructures as a function of LC amount on the nano-bowls due to the nano-confinement and the surface topography of the nano-bowls. The surface topography-mediated self-assembly made the new self-assembled LC structure that would not be able to be spontaneously produced upon cooling from isotropic to B4 phase, even in same LC molecule. Our resulting achievement is important for not only leading to the formation of the advanced LC nano-structures, but also applications in advanced nano-patterning tools
저자 류성호1, 윤동기1, 김한임1, 이선희2, 차윤정1, Dong Chen3, Eva Korblova3, David M. Walba3, Noel A. Clark3
소속 1KAIST, 2KASIT, 3Univ. of Colorado
키워드 Self-assembly; Liquid crystal; b4 phase; confined geometry
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