화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2013년 봄 (04/11 ~ 04/12, 대전컨벤션센터)
권호 38권 1호
발표분야 분자전자 부문위원회
제목 High Ambipolar Mobilities in OFETs Based on Dithienothiophene and Diketopyrrolopyrole
초록 Donor-acceptor type conjugated polymer, PDTDP, containing dithienothiophene (DTT) and diketopyrrolopyrrole (DPP) was synthesized by stille polycondensation. The polymer showed small optical band gap of 1.42 eV in film and HOMO level of 5.09 eV. The change in crystallinity and morphology of the polymer were investigated with the various annealing temperatures through XRD and AFM. The OFETs in all annealing condition exhibited ambipolar transport properties and the highest values were reached to 1 cm2•V-1•S-1. According to the highly ambipolar characteristics, the polymer complementary inverters were fabricated and showed the output voltage gain over 25. PDTDP fabricated from blends with PC71BM also exhibited good performance in PSCs with a power conversion efficiency (PCE) of 4.45 %, a open-circuit voltage (VOC) of 0.67 V, a short-circuit current density (JSC) of 10.8 mA•cm-2, and a fill factor (FF) of 0.62 under AM 1.5G irradiation.
저자 김인복, 김동윤, 장수영, 김영아, 유병관, 김동유
소속 광주과학기술원
키워드 유기전자소자; OFETs; OSCs
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