화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2015년 봄 (04/08 ~ 04/10, 대전컨벤션센터)
권호 40권 1호
발표분야 고분자가공/복합재료
제목 Graphene size control via a mechanochemical method and its electroresponsive behavior
초록 Highly dispersible graphene oxide (GO) sheets of uniform submicrometer size were successfully fabricated from pristine graphite using a simple mechanochemical process. Ball-milled GO can be used as an electrorheological (ER) material because of its small particle size, low conductivity, and outstanding dispersibility in silicone oil. We found that the 2-h ball-milled GO-based ER fluid had the best ER performance (shear stress of 78.5 Pa and 630% ER efficiency). The response time to form a fibrillar structure along the applied electric field direction and the recovery time decreased with increasing ball-milling time. Additionally, the retarded settling velocity of isolated GO sheets and the electrostatic repulsion between oxygen functional groups on the GO sheets combined to improve the anti-sedimentation property. The ability to control the size of graphene sheets is a great opportunity to advance graphene commercialization in a high-quality, scalable production setting.
저자 신근영1, 박종혁1, 이상수1, 장정식2
소속 1한국과학기술(연), 2서울대
키워드 Graphene; Size control; Ball-milling; Electrorheology
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