초록 |
Highly dispersible graphene oxide (GO) sheets of uniform submicrometer size were successfully fabricated from pristine graphite using a simple mechanochemical process. Ball-milled GO can be used as an electrorheological (ER) material because of its small particle size, low conductivity, and outstanding dispersibility in silicone oil. We found that the 2-h ball-milled GO-based ER fluid had the best ER performance (shear stress of 78.5 Pa and 630% ER efficiency). The response time to form a fibrillar structure along the applied electric field direction and the recovery time decreased with increasing ball-milling time. Additionally, the retarded settling velocity of isolated GO sheets and the electrostatic repulsion between oxygen functional groups on the GO sheets combined to improve the anti-sedimentation property. The ability to control the size of graphene sheets is a great opportunity to advance graphene commercialization in a high-quality, scalable production setting. |