화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2017년 봄 (05/10 ~ 05/12, 광주 김대중컨벤센센터(Kimdaejung Convention Center))
권호 21권 1호
발표분야 환경에너지
제목 The effect of rhenium addition to carbon-supported platinum-rhenium catalysts in the electrocatalytic oxidation of glycerol
초록 Glycerol is valuable byproduct in the production of biodiesel and fatty acids. The electrochemical conversion of glycerol is a promising technology that can produce valuable chemicals such as dihydroxyacetone, glyceraldehyde, and glyceric acid by selective oxidation reaction and electrical energy by a full oxidation reaction. In this study, we investigate PtRe/C catalysts for electrocatalytic glycerol oxidation in acidic electrolyte. PtRe/C catalysts with different Pt/Re atomic ratios are synthesized by the impregnation method with subsequent heat treatment in H2 atmosphere and characterized by using XRD, TEM, and XPS. The electrocatalytic conversion of glycerol over the PtRe/C catalysts are investigated using CV and CA with the reaction product analysis by HPLC.
저자 김영민, 한지수, 김형주, 채호정
소속 한국화학(연)
키워드 PtRe catalyst; glycerol; electrocatalysis
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