화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2022년 봄 (04/20 ~ 04/23, 제주국제컨벤션센터)
권호 28권 1호, p.511
발표분야 [주제 8] 에너지 저장
제목 Fabrication of hierarchical tree-like Fe-Co-P@Ni(OH)2 core-shell nanowire/nanosheet arrays as advanced electrode material for asymmetric supercapacitors
초록 Transition metal phosphides (TMPs) have been widely investigated for supercapacitors because of their high electrical conductivity, excellent redox activity, and metalloid feature. TMP-based materials suffer from poor rate capability and inferior long-term cyclic efficiency, which inhibit their useful practical applications. In this study, hierarchical Fe-Co-P@Ni(OH)2 core@shell architecture was synthesized on a 3D nickel foam. The Fe-Co-P@Ni(OH)2 material as positive electrode material shows an ultra-high specific capacity of 380.61 mA h g-1 at 5 mA cm−2 and an good cycling stability performance (~ 90% after 5000 cycles). The polyacrylonitrile derived nitrogen doped carbon nanofiber (NCF) as negative electrodes shows 44.5 mA h g−1 at 5 mA cm−2. Moreover, the assembled Fe-Co-P@Ni(OH)2//NCF asymmetric supercapacitor device delivers a high energy density of 65.09 W h kg−1 at 530.06 W kg−1 and an excellent cyclic stability of 91% after 5000 cycles.
저자 CHEN JIASHENG, Parthasarathi Bandyopadhyay, 김은미, 정상문
소속 충북대
키워드 에너지 환경(Energy and Environment)
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