화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2015년 봄 (04/29 ~ 05/01, BEXCO (부산))
권호 19권 1호
발표분야 (전기화학) 에너지변환/저장을 위한 전기화학적 원리Ⅱ
제목 Preparation of Ptshell-Pdcore Electrocatalyst for Alcohol Oxidation
초록 Carbon-supported Ptshell-Pdcore electrocatalyst was synthesized by electroless deposition and galvanic displacement. The catalyst was active and stable for the oxidation of both methanol and ethanol. The stability of Ptshell-Pdcore toward alcohol oxidation was attributed to the modified electronic characteristic of the Pt over-layer in the Ptshell-Pdcore, leading to its weak binding with COad. The binding property of the surface Pt with COad, and the facile oxidation of COad by OHad were investigated by X-ray spectroscopy, and by successive COad-stripping experiment, respectively.
저자 최인수1, 권오중2
소속 1강원대, 2인천대
키워드 Platinum; palladium; catalyst; methanol; ethanol; oxidation
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