화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2010년 가을 (10/07 ~ 10/08, 대구 EXCO)
권호 35권 2호
발표분야 고분자 가공/복합재료
제목 Change of Miscibility Window of PC and PMMA by adding Multiwall Carbon Nanotubes
초록 The blends of polycarbonate (PC) and poly(methyl methacrylate) (PMMA) are well known to be miscible around room temperature and be partially miscible at the temperature higher than a critical point. This behavior is well known as a lower critical solution temperature (LCST) behavior. We prepared transparent PC-PMMA films and obtained LCST curve. We calculate binodal and spinodal phase separation curves by Flory-Huggins theory. The cloud points are well consistent with the spinodal phase separation curve calculated by F-H theory as reported elsewhere. We demonstrated the phase behavior of PC-PMMA blends are changed by adding a small amount of multiwall carbon nanotube. Model calculations are also performed to analysis the change of phase behavior.
저자 배도영1, 오석빈2, 최승렬2, 유승찬2, 이헌상2
소속 1동아대, 2삼양사 중앙(연)
키워드 Polycarbonate; PC; PMMA; MWCNT; LCST
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