화학공학소재연구정보센터
학회 한국화학공학회
학술대회 1997년 봄 (04/25 ~ 04/26, 동국대학교)
권호 3권 1호, p.65
발표분야 공업화학
제목 Freeman & Carroll 식과 Kissinger 식에 의한 DGEBA-CTBN/MDA 계의 열분해 활성화
초록 To test thermal characteristics of epoxy resin pretreated with rubber copolymer astoughening agent, thermal decomposition activation energy was calculated by Freeman &Carroll equation and Kissinger equation. When the system was scanned by TGA, TG graphwas decreased with the increment of temperature and the graph sharply decreased from 356.6℃. Total weight loss of this system was 86.39 % and the fraction of weight loss from 356.6℃ to 501℃ was 80.72 %. Thermal decomposition temperature(Td) was about 370℃. Thermaldecomposition activation energy increased with the increment of heating rates of TGA andthe value of DGEBA-CTBN/MDA system was larger than that of DGEBA/MDA/CTBNsystem.
저자 송영욱, 심미자, 김상욱
소속 서울시립대
키워드 CTBN; Freeman & Carroll equation; Kissinger equation; Thermal decompoisition activation
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