| 학회 | 한국화학공학회 |
| 학술대회 | 2010년 가을 (10/21 ~ 10/22, 대전컨벤션센터) |
| 권호 | 16권 2호, p.1685 |
| 발표분야 | 에너지 |
| 제목 | Energy Gasuptake kinetics of thermally-expanded THFclathrate hydrate |
| 초록 | In this study, we measured the gasuptake kinetics of thermally-expanded THF hydrates in various energy gas and found much faster absorption tendency on thermally-expanded THF hydrate. In THF + Gas hydrate, THF molecules fill the large cage and small gas molecules fill the small cage. When thermal cycle(step heating from 77K to 270K)is applied on this gas hydrate, small gas molecules escaping the small cage leaving expanded lattice parameter by thermal motion. This thermally-expanded THF hydrate can be absorb gas molecules of interest such as H2, CH4, etc. Much faster absorption tendency was shown in thermally-expanded THF hydrate for both H2, CH4 was achieved. Repetition of thermal cycle also have effective gas absorption kinetics. |
| 저자 | 고동연, 김대옥, 이 흔 |
| 소속 | 한국과학기술원 |
| 키워드 | THF hydrate; Clathrate; Gas Uptake |
| 원문파일 | 초록 보기 |
