학회 |
한국화학공학회 |
학술대회 |
2007년 봄 (04/19 ~ 04/20, 울산 롯데호텔) |
권호 |
13권 1호, p.541 |
발표분야 |
에너지/환경 |
제목 |
Enhanced performance of solid state dye sensitized solar cells with e-beam irradiated composite polymer electrolytes |
초록 |
The use of polymer electrolytes in dye-sensitized solar cells has been a viable and promising alternative for the high performance, long-term stability and successful removal of the traditional liquid electrolytes. In the present study, we are attempted to prepare a noble heteropolyacids (HPAs)-polymer composite material with irradiation of electron beam (e-beam) with a source 1.3 MeV and dose rate of 15 kGy/min. Finally, the modified composite with iodine/iodide was applied as a polymer gel electrolyte for the fabrication of solid-state DSSC. Our results shows typical photocurrent–voltage (I-V) curves of fabricated DSSCs with VOC of 0.588 volt and ISC of 9.68 mA/cm2 with 3.35% overall conversion efficiency under 100mW/cm2 illumination. e-beam irradiation on the composite materials is essential step to increase ionic conductivity of composite and performance in device, which is a noble and simple technique. The prepared composite materials were characterized by XRD, FT-IR, DSC, TGA, ionic conductivity and photovoltaic performance tests. |
저자 |
M. Shaheer Akhtar, 전지민, 이현철, 김기주, 양오봉
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소속 |
전북대 |
키워드 |
dye sensitized solar cell; solid electrolyte
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E-Mail |
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원문파일 |
초록 보기 |