화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2007년 봄 (04/19 ~ 04/20, 울산 롯데호텔)
권호 13권 1호, p.541
발표분야 에너지/환경
제목 Enhanced performance of solid state dye sensitized solar cells with e-beam irradiated composite polymer electrolytes
초록 The use of polymer electrolytes in dye-sensitized solar cells has been a viable and promising alternative for the high performance, long-term stability and successful removal of the traditional liquid electrolytes. In the present study, we are attempted to prepare a noble heteropolyacids (HPAs)-polymer composite material with irradiation of electron beam (e-beam) with a source 1.3 MeV and dose rate of 15 kGy/min. Finally, the modified composite with iodine/iodide was applied as a polymer gel electrolyte for the fabrication of solid-state DSSC. Our results shows typical photocurrent–voltage (I-V) curves of fabricated DSSCs with VOC of 0.588 volt and ISC of 9.68 mA/cm2 with 3.35% overall conversion efficiency under 100mW/cm2 illumination. e-beam irradiation on the composite materials is essential step to increase ionic conductivity of composite and performance in device, which is a noble and simple technique. The prepared composite materials were characterized by XRD, FT-IR, DSC, TGA, ionic conductivity and photovoltaic performance tests.
저자 M. Shaheer Akhtar, 전지민, 이현철, 김기주, 양오봉
소속 전북대
키워드 dye sensitized solar cell; solid electrolyte
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