화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2008년 가을 (11/12 ~ 11/14, ICC 제주)
권호 12권 2호
발표분야 접착제도료잉크 심포지엄
제목 The Technical Design of UV Curable Polyurethane Dispersions
초록 UV curable polyurethane dispersions(UV-PUDs) have been synthesized from polyisocyanate and ether type polyol with different types of capping agent (2-hydroxyethylacrylate (HEA), pentaerythritol triacrylate(PETA), aminopropyl triethoxy silane (APTES)) and prepolymer chain length (Mp). The PUD cast films were tack free prior to cure and UV cure provided the film with high solvent and yellowing resistances, and high surface properties together with high mechanical strength.As APTES partially replaces HEA gel fraction and Tg decreased due to the decreased crosslink density, whereas hardness and contact angle increased due to the filler and hydrophobic nature of the silicon compound. Notably, the thermal degradation temperature of the UV-PUD has been increased by about 30-40℃ with at 3% APTES.
저자 Byoung-Uk Ahn1, Jae-Hong Park2
소속 1Chokwang Paint Co., 2Ltd.
키워드 Polyurethane; Polyurethane Dispersions; PU; UV Cure; UV
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