화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2011년 가을 (10/06 ~ 10/07, 김대중 컨벤션센터)
권호 36권 2호
발표분야 고분자합성-구조제어중합
제목 TheSyntehsis ofEthylene/1-Decene/para-Methylstyrene Terpolymer
초록 In this study, we synthesized ethylene/1-decene/para-methylstyrene terpolymer made of mainly ethylene. For the synthesis of the terpolymer, we used 300mL of high-pressure reactor and bridged type Zr metallocene catalyst system. Catalytic activity increases as the contents of 1-decene increases, whereas it decreases as the contents of para-methylstyrene increases. After purification procedures of terpolymer by soxhlet distillation method, we measured catalytic activity of the terpolymer. we verified molecular weight and molecular weight distribution by high-temperature GPC. We characterized the structure of the terpolymer by Infrared spectroscopy and proton NMR(Nuclear Magnetic Resonance).
저자 김현기1, 김동현1, 이범재2, 조을룡3
소속 1한국생산기술(연), 2충남대, 3한국기술교육대
키워드 Terpolymer; 1-Decene; para-Methylstyrene
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