화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2018년 가을 (10/10 ~ 10/12, 경주컨벤션센터)
권호 43권 2호
발표분야 고분자가공/복합재료
제목 Controlled Evaporative Self-assembly of Molecularly Imprinted Polymers (MIPs) and PMMA blend solution for Highly Sensitive Detection of 2,4-D
초록 Molecularly imprinted polymers (MIPs) have amassed the attention of researchers as a recognition element in chemo/biosensors, chromatography and bio-analysis due to specifically bind a chemical species. Herein, we report highly ordered MIPs and polymethyl methacrylate (PMMA) via controlled evaporative induced self-assembly for the detection of 2,4-dichlorophenoxyacetic acid (2,4-D) in an aqueous solution. When a droplet was loaded within a sphere-on-flat geometry, the evaporative induced pinning-depinning (i.e., "stick-slip") motion of solution at the droplet periphery lead to the spontaneous formation of well-organized concentric rings. This facile non-photolithographic approach of stick-slip guided surface patterning of MIP blend solution at room temperature and pressure provides a realistic alternative avenue towards constructing sensing devices for the determination of herbicides in a simple, robust, and cost-effective manner.
저자 이지혜1, 홍석원1, 박진영2, 양진철2, Saifullah Lone1
소속 1부산대, 2경북대
키워드 molecular imprinting; self-assembly; polymer; sensor
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