화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2015년 가을 (11/04 ~ 11/06, 제주국제컨벤션센터(ICCJEJU))
권호 19권 2호
발표분야 우수논문(구두)_박사과정
제목 Synergetic effect on selective catalytic reduction of NOx with NH3 over  overloaded W and Ce on V2O5/TiO2 catalysts
초록 W and Ce are known to be a good promoter to improve selective catalytic reduction (SCR) activity for V2O5/TiO2 catalysts. This work aimed at finding the optimum ratio and loading of promoters (W and Ce) on V2O5/TiO2 catalyst in order to improve SCR reactivity in low temperature region and to minimize N2O formation in high temperature region. It was found that W and Ce overloaded V2O5/TiO2 catalyst such as W/Ce/V/TiO2 (15:15:1 wt%) showed the most remarkable DeNOx properties over the wide temperature region. Additionally, this catalyst significantly suppressed N2O formation during SCR reaction, especially in high temperature region (350 - 400oC). Based on the characterization results, it was found that such superior activity originated from the improved reducibility and morphology of W and Ce species on V2O5/TiO2 catalyst when they are incorporated together at high loading.
저자 이황호, 송인학, 김도희, 윤승희
소속 서울대
키워드 Selective catalytic reduction; V2O5/TiO2; NOx; N2O
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