| 학회 |
한국고분자학회 |
| 학술대회 |
2007년 봄 (04/12 ~ 04/13, 제주 ICC) |
| 권호 |
32권 1호 |
| 발표분야 |
고분자와 연료전지 |
| 제목 |
Nafion/sulfonated poly phenylsilsequioxane nanocomposite as high temperature proton exchange membranes |
| 초록 |
Nafion/sulfonated poly(phenylmethyl silsequioxane) (PPSQ) composite membranes are fabricated using homogeneous dispersive mixing and solvent casting method for direct dimethyl ether fuel cell (DDMEFC) applications operated above 100oC. This composite membrane showed lower fuel crossover and higher proton conductivity compared to Nafion 115 and Nafion casting membrane at high temperature. The cell performances of Nafion/sPPSQ composite membranes are measured and compared with Nafion 115 and Nafion/unsulfonated PPSQ casting composite membrane at temperature ranging from 100oC to 120oC and at pressures from 1 atm to 2 atm. It was found that Nafion/sPPSQ composite membranes have better single cell performances than Nafion 115 and Nafion/unsulfonated PPSQ casting composite membrane. |
| 저자 |
남승은1, 김상옥1, 김상균1, 강영구1, 이규호1, 이재욱2
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| 소속 |
1한국화학(연), 2서강대 |
| 키워드 |
direct fuel cell; dimethylether; nafion; polyphenylsilsequioxane
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| E-Mail |
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