| 학회 |
한국공업화학회 |
| 학술대회 |
2008년 봄 (05/09 ~ 05/10, 한양대학교(안산)) |
| 권호 |
12권 1호 |
| 발표분야 |
고분자 |
| 제목 |
Anhydrous proton conducting polymer electrolytes based on mesoporous silica material-PVP/poly(vinylphosphonic acid)-heterocycle composite membrane |
| 초록 |
Triazole effectively promotes proton conductivity of materials under anhydrous conditions. The proton conduction in triazole was proposed as the transfer of protons between neighboring protonated and unprotonated guest molecules by Grotthus mechanism. Mesoporous silica SBA-15 was utilized to increase the proton conductivity through the formation of proton conductive pathway by reacting with acid groups in triazole. This approach could also prevent from leaching out of triazoles under fuel cell operation. The SBA-15/triazole/PVP-PVPA membranes showed the proton conductivity of 5.42 X 10-3 S/cm at 150 °C and low humidity (~10%). |
| 저자 |
박선준, 이동훈, 강용수
|
| 소속 |
한양대 |
| 키워드 |
Nafion; PEMFC; Triazole; SBA-15; Mesoporous silica
|
| E-Mail |
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