화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2021년 가을 (11/03 ~ 11/05, 대구 엑스코(EXCO))
권호 25권 2호
발표분야 포스터-환경·에너지
제목 Understanding of the Phenomenon that Occurred During Contact with the Zeolite LTA Membranes and Water: Effect of Each Synthesis Step on the Zeolite LTA Membranes
초록 Zeolite LTA is used in the dehydration process due to its high hydrophilicity and appropriate pore size. We investigated the phenomenon that occurred during contact of the LTA zeolite membrane with water. When the zeolite LTA membrane contacted with water, impurity layer on the surface of the membrane was removed. After the water contact time of about 100-200 hours, the structure of the zeolite LTA was mostly damaged and the dehydration performance of membrane was also sharply decreased. The optimal contact time with water for high H2O flux and separation factor was ~12 h. Fluorescence confocal optical microscopy (FCOM) analysis was used to confirm the process of the degradation of the zeolite LTA membrane. In addition, in order to obtain a zeolite LTA membrane with high dehydration performance, it is important to have an appropriate number of dip-coating and waiting time of seed suspension in the synthesis process.
저자 김표섭, 최정규
소속 고려대
키워드 zeolite; membrane; pervaporation; dealumination
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