화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2020년 가을 (10/05 ~ 10/08, 부산컨벤션센터(BEXCO))
권호 45권 1호
발표분야 고분자가공/복합재료
제목 Synthesis and properties of PI-silica composites  containing silane coupling agent  
초록 Polyimides (PI) are generally classified as thermally stable polymers due to the excellent mechanical strength and the thermal. Silica has been most investigated as an inorganic filler for the composites because of improvement in the thermal and mechanical properties. The PI-silica composites were prepared from poly(amic acid) (PAA) solution as precursor. Pristine PI and PI-silica composites could be obtained via thermal imidization of PAA produced with BPDA and ODA in DMAc. The content of silica in the composites was 1, 3 and 5 wt% with the use of silane coupling agent (SCA) to improve dispersion of silica in the matrix. And the thermal imidization of PAA in composites was heated for 1h at 100℃, 30 min at 200℃ and 1h at 350℃ to adapt PI form. The PI-silica composites were characterized with thermal, mechanical and morphological properties. The results demonstrated that the addition of small amount of silica and SCA led to the improvement in thermal and mechanical properties.
저자 장시훈1, 박준철1, 임다정1, 박진경1, 박수일2, 박노형1
소속 1한국생산기술(연), 2연세대
키워드 Polyimide (PI); Silica; Silane coupling agent (SCA); Imidization; Composites
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