화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2022년 봄 (04/06 ~ 04/08, 대전컨벤션센터)
권호 47권 1호
발표분야 고분자합성
제목 In situ thermal induced polymeric electrolyte with comparable conductivity and improved safety for Li-ion cell
초록 Rechargeable Li-ion batteries (LiBs) have acted as an essential part in our daily lives, ranging from portable consumer electronic devices to large-scale transport equipment like electric vehicles. For overcoming interfacial drawbacks and enhancing polymer electrolyte safety, in-situ polymerization is considered one of most promising approaches for enabling interfacial issues between electrolyte and electrodes. Herein, we observed the in-situ thermal induced electrolytes based on epoxy-group with LiFSI as an initiator, and a varies of technologies were applied into investigating structure characters, physicochemical properties, and electrochemical performances of as prepared solid-state polymer electrolytes. The proton nuclear magnetic resonance (1H-NMR) and Fourier transform infrared (FTIR) revealed the polymerization was successful. The conductivity of as-prepared electrolyte could over 1 mS/cm at 30 ℃. Moreover, the obtained electrolyte also exhibited good batteries performance.
저자 WEI ZHANG1, 윤수진2, 임현민2, 장기석2, 배완수2, 박성준2, 전민혁2, 장호현2, 김환기2
소속 1Konkuk Univ., 2건국대
키워드 in situ; polymer electrolyte; conductivity; Li-ion cell
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