학회 |
한국고분자학회 |
학술대회 |
2014년 가을 (10/06 ~ 10/08, 제주 ICC) |
권호 |
39권 2호 |
발표분야 |
분자전자 부문위원회 |
제목 |
Enhanced Efficiency and Air stability of Polymer Solar Cell with modifed PEDOT:PSS buffer layer using polymeric additive |
초록 |
In most of the bulk heterojunction (BHJ) OSCs, poly(4-styrene sulfonate)-doped poly(3,4-ethylenedioxythiophene (PEDOT:PSS) is widely used as hole transport layers (HTL). However, PEDOT:PSS accelerates the degradation of OSCs due to its highly hygroscopic and acidic nature. To solve this problem, PEDOT/PSS was modified to have a resistance from water using polymeric additive. As a results, power conversion efficiency(PCE) increased from 2.57% to 3.11% by 21% and half-life times also increased around 3.6times. The electrical and morphological properties of modified PEDOT/PSS was analyzed by X-ray photoelectron spectroscopy(XPS), Kelvin probe, 4-point probe meter and atomic force microscopy(AFM) respectively. This method is very simple on the production process and shows a lot of applicability in various organic electric device such as OPV, OLED, OTFT etc.. |
저자 |
이정준1, 이승환1, 박홍관2, 이선종3, 김선주4, 김중현1
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소속 |
1연세대, 2코오롱인더스트리, 3Univ. of Michigan, 4중앙대 |
키워드 |
Organic photovoltaic (OPV); PEDOT:PSS; Polymeric additive; Work function; Air stability
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E-Mail |
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