화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2014년 가을 (10/06 ~ 10/08, 제주 ICC)
권호 39권 2호
발표분야 분자전자 부문위원회
제목 Enhanced Efficiency and Air stability of Polymer Solar Cell with modifed PEDOT:PSS buffer layer using polymeric additive
초록 In most of the bulk heterojunction (BHJ) OSCs, poly(4-styrene sulfonate)-doped poly(3,4-ethylenedioxythiophene (PEDOT:PSS) is widely used as hole transport layers (HTL). However, PEDOT:PSS accelerates the degradation of OSCs due to its highly hygroscopic and acidic nature. To solve this problem, PEDOT/PSS was modified to have a resistance from water using polymeric additive. As a results, power conversion efficiency(PCE) increased from 2.57% to 3.11% by 21% and half-life times also increased around 3.6times. The electrical and morphological properties of modified PEDOT/PSS was analyzed by X-ray photoelectron spectroscopy(XPS), Kelvin probe, 4-point probe meter and atomic force microscopy(AFM) respectively. This method is very simple on the production process and shows a lot of applicability in various organic electric device such as OPV, OLED, OTFT etc..
저자 이정준1, 이승환1, 박홍관2, 이선종3, 김선주4, 김중현1
소속 1연세대, 2코오롱인더스트리, 3Univ. of Michigan, 4중앙대
키워드 Organic photovoltaic (OPV); PEDOT:PSS; Polymeric additive; Work function; Air stability
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