화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2018년 가을 (10/31 ~ 11/02, 제주국제컨벤션센터(ICC JEJU))
권호 22권 2호
발표분야 고분자_포스터
제목 Quarternery Ammonium Bromide Based Small Molecule Electrolyte Doped ZnO as Electron Trasnport Layer in Polymer Solar Cells
초록 The organic electrolyte based on quaternary ammonium bromide with hydroxyl group doped ZnO as the electron transport layer (ETL) for the polymeric solar cells are prepared by the sol-gel method. ZnO layers doped with N,N,N,N,N,N-hexakis(2-hydroxyethyl)butane-1,4-diaminiumbromide (H1) was fabricated as ETL in inverted solar cell devices. The presence of small molecules is characterized by X-ray photoelectron spectroscopy. The work function of H1 doped ZnO measured by Kevin Probe microscopy is higher than pristine, the work function value of ZnO doped is 4.0 eV then the pristine is 4.5 eV. The interface dipole from hydroxyl grup and quarternary ammonium bromide between the ZnO layer and the active layer plays an important role in power conversion efficiency (PCE). As the result, the PCE enhanced up to 8.87% compared to pristine ZnO 7.4%.
저자 sabrina aufar salma, 김동근, 이준호, 정미진, 진호철, Ratna dewi maduwu, 김주현
소속 부경대
키워드 sol gel; organic electrolyte; polymer solar cell; dopped ZnO
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