화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2011년 봄 (04/07 ~ 04/08, 대전컨벤션센터)
권호 36권 1호
발표분야 기능성 고분자
제목 Synthesis and Photovoltaic Properties of Cabazole-BasedLow-Bandgap Copolymers That Contain Electron-Withdrawing Benzimidazole Derivatives Moiety for OPVs.
초록 Polymeric solar cells (PSCs) have attracted considerable attention for their great advantages over existing inorganic solar cells, such as ease of processing, light weight, flexibility, low cost, and so forth. New type for OPVs is D-A polymers which have two absorption band in UV-vis absorption spectra. These UV absorption bands can cover large area of solar spectrum. Recently, derivatives of PCPDTBT were synthesized and reported high photovoltaic properties. We designed and synthesized new acceptor material for D-A polymers. Novel conjugated polymer, Poly(N-9’-heptadecanyl-2,7-carbazole-co-5,5-(4’,7’-di-2-thienyl-2,2-(1,5-pentamethylene)-2H-benzimidazole)) (PCDTPMBI), was synthesized by Stille coupling. The Power conversion effciciency is about 0.2%.
저자 송수희1, 김기환2, 조희진1, 박혜지1, 진영읍3, 김진영2, 서홍석1
소속 1부산대, 2울산과학기술원, 3부경대
키워드 OPV; Polymer
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