| 학회 |
한국고분자학회 |
| 학술대회 |
2012년 봄 (04/12 ~ 04/13, 대전컨벤션센터) |
| 권호 |
37권 1호 |
| 발표분야 |
기능성 고분자 |
| 제목 |
Easily Attainable Phenothiazine-Based Polymers for Polymer Solar Cells: Advantage of Insertion of S,S-Dioxides into its Polymer for Inverted Structure Solar Cells |
| 초록 |
PPTDTBT and PPTDTBT-SS are fully characterized by UV-vis absorption, electrochemical cyclic voltammetry, X-ray diffraction (XRD), and DFT theoretical calculations. We find that the maximum absorption of PPTDTBT is not only markedly red-shifted with respect to that of PPTDTBT-SS but also its band gap as well as molecular energy levels are readily tuned by the insertion of S,S-dioxides into the polymer. The main interest is focused on the electronic applications of the two polymers in organic field-effect transistors (OFETs) as well as conventional and inverted polymeric solar cells. PPTSTBT is a typical p-type polymer semiconductor for OFETs and conventional PSCs based in this polymer and PC71BM show a power conversion efficiency (PCE) of 1.69%. In case of PPTDTBT-SS, the devices characteristics result in: 1 order of magnitude higher hole mobility than that obtained with PPTDTBT ans improved performance of the inverted PSCs (1.22%), compared to its conventional devices. |
| 저자 |
염혜림1, 김경식1, 양창덕1, 김진영1, 서정화2, 조신욱3
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| 소속 |
1울산과학기술대, 2동아대, 3울산대 |
| 키워드 |
Polymer Solar Cells; Inverted Structure Solar Cells
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| E-Mail |
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