| 학회 |
한국공업화학회 |
| 학술대회 |
2022년 봄 (05/11 ~ 05/13, 제주국제컨벤션센터(ICC JEJU)) |
| 권호 |
26권 1호 |
| 발표분야 |
포스터-고분자 |
| 제목 |
Engineering Backbone Building Units and Regioregularity of Polymerized Small-Molecule Acceptors for Efficient All-Polymer Solar Cells with High Electron Mobility |
| 초록 |
Charge transport ability of polymer acceptors is an essential requirement for achieving high power conversion efficiencies of all-polymer solar cells (all-PSCs). Here, we design a new series of the polymerized SMA-based PA materials (Y5-A-B, A= selenophene (Se)/ biselenophene (BiSe) and B= In/Mix/Out) for enhancing the µe and, thus, PCE of all-PSCs. In detail, i) donating moieties (Se/BiSe) and ii) backbone regioregularities (In/Mix/Out) are two-dimensionally controlled to yield six different PAs. We successfully demonstrate the importance of this two-dimensional control the electrical properties of the PAs. The most interesting finding here is that the In/Mix/Out regioisomer effects on the PA¬ properties are completely different depending on the Se/BiSe donating unit in the PA. Overall, we observe a strong, direct relationship between the µe and PCE of all-PSCs. |
| 저자 |
이진우1, 서수덕1, Cheng Sun2, 김윤희2, 권순기2, 김범준1
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| 소속 |
1KAIST, 2경상대 |
| 키워드 |
All polymer solar cell; Power conversion efficiency; Polymerized small molecule acceptor
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| E-Mail |
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