화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2017년 봄 (05/10 ~ 05/12, 광주 김대중컨벤센센터(Kimdaejung Convention Center))
권호 21권 1호
발표분야 에너지저장변환
제목 Synthesis of the hollow shell structured-ZrO2 and its application for self-humidifying proton exchange fuel cells(PEMFCs)
초록 Nafion has been known as the polymer with excellent proton conductivity in the presence of water. Self-humidifying PEMFC was studied to overcome this problem. In this study, the electrode was prepared by Pt-C/Pt-H-ZrO2 as dual catalyst electrode for self-humidifying PEMFC. Hollow shell of ZrO2 (H-ZrO2) was synthesized by sol-gel method using SiO2 as a template. H-ZrO2 was confirmed by Brunauer-Emmet-Teller method (BET), scanning electron microscopy (SEM) and high resolution transmission electron microscope (HR-TEM). BET analysis shows the increase of surface area of H-ZrO2 compared to that of SiO2@ZrO2. Successfully prepared H-ZrO2 exhibits high water uptake. The cell test was conducted under various relative humidity (RH). The dual catalyst electrode comprised by H-ZrO2 and Pt-C shows a possible route for self-humidifying PEMFC.
저자 고영돈, 최범석, 김화중
소속 건국대
키워드 Cell performance; Dual catalyst electrode; Hollow shell; Self-humidifying PEMFC
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