학회 | 한국공업화학회 |
학술대회 | 2005년 가을 (10/28 ~ 10/29, 건국대학교) |
권호 | 9권 2호 |
발표분야 | 정밀화학 |
제목 | New Synthetic Method for a,b-Bis(trichlorosilyl)alkanes. Double Silylation of Olefins with Trichlorosilane in the Presence of tetrabutylphosphonium chloride |
초록 | Reaction of olefins such as styrene, terminal and internal alkenes with trichlorosilane in the presence of tetrabutylphosphonium chloride as a catalyst at 180 oC gave the bis-silylation products, bis(chlorosilyl)alkanes, in fair to excellent yields (43 - 86%) depending upon the olefin substituents. |
저자 | 임원철, 한준수, 강승현, 유복렬 |
소속 | 한국과학기술(연) |
키워드 | Bis(silyl)methanes; Si–C coupling; trichlorosilane |
bryoo@kist.re.kr |