화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2006년 가을 (10/27 ~ 10/28, 고려대학교)
권호 12권 2호, p.1652
발표분야 분리기술
제목 Development of new photoacoustic signal generation theory for in situ concentration profiling on permeant/membrane system
초록 Microporous molecular sieve membranes have potential to revolutionize several industrially important separations. Considerable research has hence been aimed at membrane composition (including guest molecule concentration) and transport properties as a function of depth. The study of membrane transport phenomena depends heavily on theoretical models (e.g., the Maxwell-Stefan equations). We are developing non-destructive, in situ methods based on photoacoustic spectroscopy to probe the depth dependence of membrane composition.
Here we present an new photoacoustic signal generation theory, to apply the non-destructive concentration profiling of molecular sieve membranes. In particular, we have applied the new theory on step-scan photoacoustic spectroscopy (SS-PAS) to depth-profile MFI zeolite membranes. The new photoacoustic theory is useful to monitor depth-profiles during in situ measurements. The monitored depth-profile is continuous and quantitative. In addition, the positions of the layer interfaces and the layer thicknesses are obtained.
저자 오원태
소속 동의대
키워드 Photoacoustics; concentration profiling; membrane; transport dynamics
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