| 학회 |
한국화학공학회 |
| 학술대회 |
2013년 가을 (10/23 ~ 10/25, 대구 EXCO) |
| 권호 |
19권 2호, p.1615 |
| 발표분야 |
에너지 |
| 제목 |
Comparative study on Cu-Ce0.8Zr0.2O2 and Cu-Ce0.2Zr0.8O2 catalysts for the low temperature water gas shift reaction |
| 초록 |
Low temperature water gas shift reaction (LT-WGS) has been carried out at a gas hourly space velocity of 72,152 h-1 over Ce(1-x)Zr(x)O2 supported Cu catalysts prepared by a co-precipitated method. The CeO2/ZrO2 ratio was systematically varied to understand beneficial effect of cubic/tetragonal phases of Ce(1-x)Zr(x)O2. 20wt% Cu loaded on cubic phase Ce0.8Zr0.2O2 exhibited higher CO conversion than 20wt% Cu loaded on tetragonal phase Ce0.2Zr0.8O2. The effect of cubic/tetragonal phases of Ce(1-x)Zr(x)O2 has been characterized by BET, XRD, N2O-chemisorption, TPR and the characterization results have been related to the activity results in LT-WGS. |
| 저자 |
나현석1, 정대운1, 장원준1, 심재오1, 한원비1, 노현석1, 정운호2, 윤왕래2
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| 소속 |
1연세대, 2에너지기술(연) |
| 키워드 |
Low temperature water gas shift reaction; Ce(1-x)Zr(x)O2; Cubic/tetragonal phase
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| E-Mail |
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| 원문파일 |
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