학회 | 한국공업화학회 |
학술대회 | 2018년 가을 (10/31 ~ 11/02, 제주국제컨벤션센터(ICC JEJU)) |
권호 | 22권 2호 |
발표분야 | 고분자_포스터 |
제목 | Catalytic performance for Suzuki-Miyaura reaction based on palladium-supported polymer by functional group |
초록 | The palladium-catalyzed Suzuki-Miyaura coupling reaction is one of the most important organic transformations for the construction of carbon-carbon bonds. Its widespread use in the synthesis of natural products, pharmaceuticals, agrochemicals, and polymers is a testament to its broad impact on the chemical science. Most Suzuki-Miyaura cross-coupling reactions are performed using palladium catalysts and the catalyst performance is largely dependent on the ligand of palladium. In this aspect, nitrogen-rich polymers have a great potential of palladium immoilized, because they have a high affinity for metals. In this study, we prepared various polymers composed of nitrogen and immobilized palladium for catalytic performance for Suzuki-miyaura cross-coupling reaction. The experimental was characterized by FT-IR, TEM, BET, SEM, GC |
저자 | 소재일, 천영걸, 류지형, 심상은 |
소속 | 인하대 |
키워드 | heterogeneous catalyst; suzuki-miyaura |