| 학회 |
한국공업화학회 |
| 학술대회 |
2019년 가을 (10/30 ~ 11/01, 제주국제컨벤션센터(ICC JEJU)) |
| 권호 |
23권 2호 |
| 발표분야 |
포스터_환경·에너지 |
| 제목 |
Selective production of monomers from lignin depolymerization in water using ZnO-Co@N-CNTs |
| 초록 |
In this study, we performed the catalytic depolymerization of Kraft lignin in water using ZnO-Co@N-CNTs catalyst and compared its activity with different catalysts. Almost complete conversion (94.0%) of lignin into alkyl-substituted cyclohexanone and phenolic species with a monomeric yield of 12.1% was achieved at 350 ºC for 6 h reaction. When the temperature was increased to 400 ºC, the monomeric yield was further increased to 24.4%. The major species were phenol and its derivatives. Moreover, a high degree of deoxygenation (72.0%) of lignin was achieved in water by ZnO-Co@N-CNTs at 350 C for 6 h reaction time. A complete comparison with different catalysts was made on the basis of lignin conversion, bio-oil yield, monomeric yield and degree of deoxygenation. The high monomeric yield and a high degree of deoxygenation in water from ZnO-Co@N-CNTs make this catalyst a potential candidate for developing an environment-friendly and cost-effective process for biochemical production. |
| 저자 |
Umair mushtaq1, 박재용2, 김재훈3
|
| 소속 |
1School of chemical engineering, 2Sungkyunkwan Univ., 3성균관대 |
| 키워드 |
Lignin; Zinc cobalt catalyst; Monomer
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| E-Mail |
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