| 초록 |
Zn(1-NaPN)2 and Zn(2-NaPN)2 were successfully synthesized. The optical properties of the synthesized compounds were measured through UV-visible and PL spectrum. The UV-visible maximum values in solution state, 485 and 486 nm for Zn(1-NaPN)2 and Zn(2-NaPN)2 respectively, have similar absorption maximum value. PL spectrum maximum values, 516 and 518 nm. In the film state, UV-visible maximum values, about 517 nm for both substances, indicated absorption of similar wavelengths. PL spectrum was shown to be about 550 nm. Zn(1-NaPN)2 and Zn(2-NaPN)2, the synthesized compounds, were measured on electrochemical kinetic properties through cyclic voltammogram (CV), and both materials showed similar oxidation voltage of about 0.7 V (vs. Ag/AgNO3). The exponent of scan rate and x value of Zn(1-NaPN)2 and Zn(2-NaPN)2 were 0.52 and 0.33, so the kinetics of Zn(1-NaPN)2 is mainly controlled by diffusion process. |
