| 학회 |
한국고분자학회 |
| 학술대회 |
2008년 봄 (04/10 ~ 04/11, 컨벤션 뷰로(대전)) |
| 권호 |
33권 1호 |
| 발표분야 |
고분자 구조 및 물성 |
| 제목 |
Self-Assembly of Rod-Disc Liquid Crystals and Biaxial Molecular Arrangements under an Electric Field |
| 초록 |
A series of new molecular discs (RDn) was synthesized via the chemical attachment of six cyanobiphenyl calamitic (rod) mesogens (R) linked to the triphenyl discotic (disc) mesogen (D) with a series of six alkyl chain linkages (n = 6-12). DSC, POM, 1D/2D WAXD, and SAED allowed us to identify three ordered phases below the isotropization temperature and molecular packings in their ordered phases. Both triphenyl discotic mesogens and cyanobiphenyl calamitic mesogens are completely interdigitated. Especially, RD12 exhibits a biaxial N molecular orientation under a DC electric field. |
| 저자 |
정광운1, Alexander J. Jing2, Bart Mansdorf3, Frank W. Harris4, Deng-Ke Yang5, Stephen Z. D. Cheng6
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| 소속 |
1전북대, 2Department of Polymer Science, 3The Univ. of Akron, 4Akron, 5Ohio 44325, 6USA |
| 키워드 |
structure; morphology; self-assembly; liquid crystal; biaxial nematic
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| E-Mail |
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