화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2015년 가을 (10/06 ~ 10/08, 대구컨벤션센터(EXCO))
권호 40권 2호
발표분야 대학원생 구두발표 (발표15분)
제목 Thermoset polymers consisting of novolac and melamine derivatives as insulators for organic thin-film transistors
초록 A potential gate dielectric material that can be cured and processed at low temperatures was designed and synthesized via the cross-linking of bisphenol A novolac (Novolac) and hexamethoxymethylmelamine (HMMM) in the presence of a catalytic amount of p-toluenesulfonic acid. The thin films of the prepared insulator, Novolac-MM, were completely solidified after cross-linking at 100 °C. Metal-insulator-metal (MIM) devices and pentacene-based p-type organic thin-film transistors (OTFTs) using the synthesized polymer as a dielectric layer were fabricated and compared to poly(vinylphenol)-based materials. Novolac-MM devices showed low leakage current (<10−8 A/cm2) and higher hole mobility (0.31 cm2/Vs) than PVP devices (0.23 cm2/Vs). Flexible OTFTs using Novolac-MM were also fabricated, and were found to be processable at low temperatures
저자 황도훈1, 곽정훈2, 김용남2, 하종운1
소속 1부산대, 2동아대
키워드 organic thin-film transistor; bisphenol A novolac; melamine; insulator
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