화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2018년 가을 (10/10 ~ 10/12, 경주컨벤션센터)
권호 43권 2호
발표분야 분자전자 부문위원회 II
제목 Develop of TPD-based Polymers for OPV Applications as Donor Materials
초록 Two conjugated thienopyrrolodione-thiophene-vinyl-thiophene (TPD-TVT)-based polymers, with one of them having an additional cyano (CN) group attached to the TVT unit, were designed and synthesized and shown to be efficient donor materials for OPV applications. Both TPD-TVT and TPD-TVTCN showed good thermal stability and appropriate solubility in chlorinated solvents, but they exhibited quite different opto-electrochemical characteristics. Also, compared to TPD-TVTCN, the TPD-TVT donor polymer displayed less aggregation, and formed a better-mixed blend with PC71BM. Solar cells we made also showed better device performances, which we attributed to more nanoscale phase aggregation.
저자 정영헌1, 김윤희1, 이지은1, 김유진2, 홍지수3, 황문찬4, 권순기5, 안태규6
소속 1경상대, 2POSTECH Organic Electronics Laboratory, 3Department of Chemical Engineering, 4Pohang Univ. of Science and Technology, 5Pohang, 6790-784
키워드 Bulk Heterojunction Solar Cells; Polymer Solar Cells; Donor Polymers
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