화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2014년 가을 (10/06 ~ 10/08, 제주 ICC)
권호 39권 2호
발표분야 분자전자 부문위원회
제목 Molecular orientation control of liquid crystalline organic semiconductors via directed self-assembly with thermal gradient for high performance OFETs
초록 We fabricated strongly textured organic semiconductor (OSC) micro patterns of the liquid crystalline small molecule by using template assisted self-assembly. The self-alignment properties of the liquid crystal phase of OSC, C10-BTBT, enable the solvent-free fabrication. In a highly ordered micropattern, the molecules of C10-BTBT were assembled through [100] direction as following the capillary flow. However, the more effective charge transport occurs along the [010] direction due to stronger intermolecular electronic coupling in C10-BTBT crystal structure. In order to enhance electrical performance, we aimed to well defined molecular orientation of smetic liquid crystal phase of C10-BTBT via changing the direction of thermal flow. As a result, we fabricated the high-performance printed organic field effect transistors (OFETs).
저자 김소희1, 김아련2, 장광석1, 김진수1, 가재원1, 홍성권1, 김윤호2
소속 1한국화학(연), 2충남대
키워드 OFETs; organic semi conductor; molecular orientation
E-Mail