화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2008년 봄 (04/23 ~ 04/25, 제주ICC)
권호 14권 1호, p.1340
발표분야 촉매 및 반응공학
제목 Oxidative Carbonylation of Aniline Using Polymer Supported Methylselenite
초록 Polymer-supported methylselenites including poly(1-methyl-3-vinylimidazolium methylselenite) and poly(1-ethyl-3-vinylimidazolium methylselenite) were synthesized from the direct polymerization of 1-methyl-3-vinylimidazolium methylselenite and 1-ethyl-3-vinylimidazolium methylselenite. The results of Fourier Transform Infrared (FT-IR) spectra and thermogravimetric analysis (TGA) clearly showed that methylselenite is tightly immobilized on the imidazolium-based polymer. The catalyst recycle test showed that the supported catalyst can be reused at least up to five times with a moderate loss of activity.
저자 전은희, 이제승, 정민석, 김훈식
소속 경희대
키워드 Oxidative carbonylation; Methylselenite; Ionic liquid; Polymer-supported; Urea; Carbamate
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