화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2021년 가을 (10/20 ~ 10/22, 경주컨벤션센터)
권호 46권 2호
발표분야 대학원생 구두발표(영어발표, 발표15분)
제목 Work Function Tunable Conducting Polymers for Hole Transport Layer Free Polymer Solar Cells
초록 Polymer solar cells (PSCs) have notable advantages such as possibility of roll-to-roll mass production. However, there is existing issues of thickness-dependent charge transport layers in large area module. In this work, one of the perfluorosulfonic acids, ethanesulfonyl fluoride, 2-[1-[difluoro-[(trifluoroethenyl)oxy]methyl]-1,2,2,2-tetrafluoro-ethoxy]-1,1,2,2,-tetrafluoro-, with tetrafluoroethylene also known as Nafion is blended with the poly(3,4-ethylenedioxythiophene):polystyrenesulfonate (PEDOT:PSS) for tuning the work function of electrodes. The films made with the blending of PEDOT:PSS and Nafion (P:N) are treated with concentrated sulfuric acid for a well-ordered crystalline structure in P:N electrodes. We fabricated hole transport layer free PSCs with P:N films as an anode. We confirmed the electrical and morphological properties of the P:N films with the various ratio of Nafion.
저자 김재영, 이광희
소속 광주과학기술원
키워드 conducting polymer; PEDOT:PSS; Nafion; electrode; HTL-free polymer solar cells; work function tuning
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