화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2009년 봄 (04/15 ~ 04/17, 호텔인터불고(대구))
권호 13권 1호
발표분야 환경에너지
제목 Excess molar volumes and refractive indices for the binary and ternary mixtures di-methyl carbonate (DMC) + Methanol + BMIM[BF4] at 298.15 K
초록 Ionic liquids (ILs) are nonvolatile solvents composed of organic cations with organic or inorganic anions. In spite of their importance and interest, a detailed knowledge on the phase quilibrium data of the mixtures containing ionic liquids in ordinary molecular solvents is very limited. In this work, densities and refractive index at 298.15 K are reported for the binary systems of Di-methyl carbonate (DMC), methanol and [BMIM][BF4]. The VE and ΔR were correlated with Redlich-Kister equation for binary systems, respectively. Additionally the ternary VE and ΔR data at 298.15 K were also predicted for system DMC + methanol +[BMIM][BF4] by using binary contribution model of Radojkovi with the binary Redlich-Kister parameters.
저자 이재연, 황인찬, 박소진
소속 충남대
키워드 VE; DMC; Methanol; BMIM; ionic liquid
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