화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2014년 가을 (10/06 ~ 10/08, 제주 ICC)
권호 39권 2호
발표분야 고분자 액정소재 기반 디스플레이
제목 Self-assembled chiral nanopore arrays with bent-core liquid crystals
초록 We introduced a novel nano-fabrication system using bent-shaped liquid crystals (LCs) as nano building blocks to achieve functional 3D- nanostructures. Bent-core LCsself-assemble into very unique superstructure called as helical nanofilaments (HNFs),which is occuredby the highly restrictive molecular packing process based on the molecular geometries.Under nano-confinement using porous anodic aluminum oxide (AAO) film, individualHNFs readily grow in linear nanoscale pores generatingchiral nanoporous structures. Both helical pitch and width of chiral pores are tuneable with sub-nanometerprecision by varying the pore size of AAObased on quantitatively controlled surface anchoring.Such hierarchically self-assembled chiral nanopore arrays can be used as a 3D-nanopatterning template with the other guest materials confined in nanoscale interstitial volumes between the HNFs and AAO, which is potentially used for chiral separation.
저자 김한임1, 이선희1, 신태주2, Eva korblova3, David Walba3, Noel Clark3, 이상복4, 윤동기1
소속 1KAIST, 2포항가속기(연), 3Univ. of Colorado, 4Univ. of Maryland
키워드 Bent-core liquid crystals; Helical nanofilament; Nano-confinement; AAO; Chiral nanopore arrays
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