화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2019년 가을 (10/30 ~ 11/01, 제주국제컨벤션센터(ICC JEJU))
권호 23권 2호
발표분야 포스터_콜로이드·계면화학
제목 Effective Fabrication and Electrochemical OER Activity of Gold Multipod Nanoparticle Core-Cobalt Sulfide Shell Nanohybrids
초록 Hybrid materials with anisotropic noble-metal nanoparticle cores and cagelike transition-metal chalcogenide shells are considered promisng materials in a wide diversity of applications. Herein, a facile preparation of gold multipod nanoparticles (GMNs) embedded within cobalt sulfide nanocage is reported. The as-prepared GMN cores- ZIF-67 shell (GMN@ZIF-67) nanostructures can act as sacrificial templates to the desired nanohybrids composed of multiple GMNs and cobalt sulfide (GMN@CoxSy) nanocages. Electrocatalytic oxygen evolution reaction (OER) of the prepared nanocatalysts reveals that a type of GMN@CoxSy nanohybrid shows a substantially lower overpotential (η) value (345 mV) compared with those of GMNs (617 mV) and CoxSy nanomaterials (418 mV) at a current density of 10 mA cm2, mainly due the highly effective core−shell interfaces as well as the optimized cobalt sulfide shells of the nanohybrids.
저자 MAIDUYHIEN, 유효종
소속 한양대
키워드 hybrid nanomaterial; cobalt sulfide; OER
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