학회 |
한국공업화학회 |
학술대회 |
2019년 가을 (10/30 ~ 11/01, 제주국제컨벤션센터(ICC JEJU)) |
권호 |
23권 2호 |
발표분야 |
포스터_환경·에너지 |
제목 |
Self-assembled monolayer of pyridine@Cu-MOF-8 nanoparticle, a new electrocatalyst for reduction of CO2 to methanol |
초록 |
The electrochemical reduction of carbon dioxide (CO2) to form methanol (MeOH) is currently a hot topic. MeOH is used as fuel additive and as solvent. There are distinct types of homo and heterogeneous catalytic systems. However, the main issues for electrochemical reduction of CO2 are formation of many byproducts, less stability of catalyst and low faradic efficiency. These key issues are not solved. In current century several types of metal oxide nanoparticle and metal organic framework-8 (MOF-8) were synthesized to address the issues such as MOF-8 and MOF-67. Same idea was adopted to produce MeOH from CO2 using binary cuprite (Cu2O) nanoparticle and MOF-8. The synthesized catalyst worked at -1.3V to form MeOH with high current and more faradic efficiency. Moreover, given catalyst could be active around 120 min without changing faradic efficiency. |
저자 |
PAWAR ATUL ASHOK, 김헌
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소속 |
명지대 |
키워드 |
Carbon dioxide; Methanol; MOF-8; Reduction reaction.
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E-Mail |
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