화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2019년 봄 (05/01 ~ 05/03, 부산 벡스코(BEXCO))
권호 23권 1호
발표분야 고분자_포스터
제목 Versatile Sensor Applications of Chiral Supramolecular Biocoordination Polymers
초록 Chiral supramolecular structures have a great potential to be used in chiral recognition, sensing, and catalysis. Here, we fabricated the novel homochiral and heterochiral biocoordination polymers (BCPs) between chiral organic ligands and Zn ions by using solvothermal reactions. In the heterochiral BCPs, we can observe a chiral self-discrimination phenomenon. Remarkably, they have multifunctional properties such as photochromatic, photoluminescent, and chemiresistive characteristics for versatile sensors. For instance, these materials can be used for detecting harzardous amines due to electron transfer from the amine to the BCPs. In addition, they can enantioselectively sense a chiral naproxen based on the different binding energies with regard to their chirality. All of these approaches provide novel ways of synthesises and applications of the BCPs
저자 안재용1, Xiaobo Shang1, 송인호1, 정관영2, 최완욱3, Hiroyoshi Ohtsu4, 이정현2, 구진영3, Bo Liu5, Masaki Kawano4, 곽상규2, 오준학1
소속 1서울대, 2UNIST, 3포항공과대, 4Tokyo Institute of Technology, 5Zhejiang Univ.
키워드 Supramolecular chirality; Biocoordination polymers; Sensors
E-Mail