학회 |
한국화학공학회 |
학술대회 |
2013년 가을 (10/23 ~ 10/25, 대구 EXCO) |
권호 |
19권 2호, p.2019 |
발표분야 |
촉매 및 반응공학 |
제목 |
Catalytic hydrodeoxygenation of eugenol over supported calcium carbonate catalysts |
초록 |
Fast pyrolysis is one of the promising processes to valorize lignocellulosic biomass to obtain liquid products known as bio-oil. Its high oxygen content, however, limits the complete replacement of fossil fuels. Therefore, processes to stabilize the oil and remove the oxygen content are required to upgrade bio-oils to obtain hydrocarbon fuels. The hydrodeoxygenation (HDO) is one of the promising methods to upgrade bio-oil. During the HDO, oxygen in the bio-oil feed is converted to water and alcohols. In this study, we investigated the HDO of eugenol, a frequently observed component in the pyrolysis oil derived from lignin, over bifunctional catalysts composed of metal nanoparticles and basic CaCO3. The catalytic HDO of eugenol in n-hexadecane as a solvent was studied in a high pressure batch reactor at 250 °C and 40 bar H2. The roles of basic CaCO3 along with metal nanoparticles on the HDO activity were studied. |
저자 |
Adid Adep Dwiatmoko1, 이마로1, 최재욱1, 서동진1, 하정명1, 김일원2
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소속 |
1한국과학기술(연), 2숭실대 |
키워드 |
Hydrodeoxygenation; Eugenol; CaCO3
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E-Mail |
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VOD |
VOD 보기 |
원문파일 |
초록 보기 |