화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2013년 가을 (10/23 ~ 10/25, 대구 EXCO)
권호 19권 2호, p.2019
발표분야 촉매 및 반응공학
제목 Catalytic hydrodeoxygenation of eugenol over supported calcium carbonate catalysts
초록 Fast pyrolysis is one of the promising processes to valorize lignocellulosic biomass to obtain liquid products known as bio-oil. Its high oxygen content, however, limits the complete replacement of fossil fuels. Therefore, processes to stabilize the oil and remove the oxygen content are required to upgrade bio-oils to obtain hydrocarbon fuels. The hydrodeoxygenation (HDO) is one of the promising methods to upgrade bio-oil. During the HDO, oxygen in the bio-oil feed is converted to water and alcohols. In this study, we investigated the HDO of eugenol, a frequently observed component in the pyrolysis oil derived from lignin, over bifunctional catalysts composed of metal nanoparticles and basic CaCO3. The catalytic HDO of eugenol in n-hexadecane as a solvent was studied in a high pressure batch reactor at 250 °C and 40 bar H2. The roles of basic CaCO3 along with metal nanoparticles on the HDO activity were studied.
저자 Adid Adep Dwiatmoko1, 이마로1, 최재욱1, 서동진1, 하정명1, 김일원2
소속 1한국과학기술(연), 2숭실대
키워드 Hydrodeoxygenation; Eugenol; CaCO3
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