학회 |
한국고분자학회 |
학술대회 |
2014년 가을 (10/06 ~ 10/08, 제주 ICC) |
권호 |
39권 2호 |
발표분야 |
분자전자 부문위원회 |
제목 |
Amphiphilic Layer-by-Layer Assembly Overcoming Solvent Polarity between Aqueous and Nonpolar Media and Its Applications to Hybrid Supercapacitor |
초록 |
Amphiphilic Layer-by-Layer assembly is a versatile methodology that allows a facile incorporation of the functional components with completely different chemistry of hydrophilic/hydrophobic properties within nanocomposite films, and furthermore combine a number of the distinctive advantages of traditional electrostatic layer-by-layer (LbL) assembly in aqueous media and covalent LbL assembly in nonpolar media. Amphiphilic LbL assembly is based on the high affinitiy between sulfonic acid-fuctionalized materials in queous media and hydrophobic metal oxide (or metal) NPs in nonpolar solvent. This approach can be extended o the preparation of functional colloids (or carbon-based materials) materials allowing the reversible phase transfer between aqueous and nonpolar media and hybrid supercapacitor electrodes with high volumetric capacitance (280 F·cm-3 at 10 mV·s-1) using reuced graphene oxide with sulfonic acid moieties and well-defined OA-Fe3O4 NPs. |
저자 |
박민경, 조진한
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소속 |
고려대 |
키워드 |
Layer-by-Layer; Reduced graphene oxide; Colloid; Supercapacitor; Nanoparticle
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E-Mail |
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