화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2014년 가을 (10/22 ~ 10/24, 대전 DCC)
권호 20권 2호, p.2027
발표분야 재료
제목 Sonochemical synthesis of palladium oxide@silica nanoparticle for the catalysis of selective alcohol oxidation with molecular oxygen
초록 Sonochemical method is easy and effective way to synthesize nanomaterial. Under ultrasound irradiation, novel metal precursor was reduced into metal nanoparticle with narrow size distribution. Additionally, catalyst supporting material was frequently used to prevent metal nanoparticles agglomeration. Most catalysts for organic chemistry are size dependent. Therefore, supported catalysts are generally applied in the reaction. In this study, we fabricated silica supported palladium oxide catalyst by ultrasound irradiation. Silica nanoparticles as supporting materials were fabricated by Stöber method. The composites have narrow size distribution and their average size of metal nanoparticle was 2.5 nm. Fabricated palladium oxide doped silica nanoparticles were applied to selective alcohol oxidation with molecular oxygen.
저자 석승환1, Muhammad Asif Hussain2, 박견주1, 최봉길2, 김정원2, 김도현1
소속 1KAIST, 2강원대
키워드 silica; palladium oxide; oxidation reaction
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