화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2015년 가을 (11/04 ~ 11/06, 제주국제컨벤션센터(ICCJEJU))
권호 19권 2호
발표분야 고분자_포스터
제목 Novel cationic photopolymerizable propenyl ethers  
초록 Several mono- and di-propenyl ethers were synthesized by the direct allylation of alcohols in the presence of base and a quaternary ammonium salt phase transfer catalyst. Then the allyl ethers were rearranged to the corresponding propenyl ethers using a strong base in high yield. Utilizing real-time infrared spectroscopy, the reactivity of the monomers in photoinitiated cationic polymerization was studied employing triarylsulfoniumsalts containing long-chain alkoxy group as photoinitiators. The monomers were shown to undergo very rapid photopolymerization.
저자 제갈영순1, 심상연2, 김기상2
소속 1경일대, 2강릉원주대
키워드 photopolymerization; photoinitiators
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