화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2021년 가을 (10/20 ~ 10/22, 경주컨벤션센터)
권호 46권 2호
발표분야 기능성 고분자
제목 All-organic piezoelectric elastomer formed by semi-crystalline polyrotaxanes
초록 The polyrotaxane (PRX), which comprises ring-shaped α-cyclodextrin threaded on linear poly(ethylene glycol), is cross-linked with a mixture of two different types of diisocyanate cross-linkers to encompass the cross-linked amorphous and non-cross-linked crystalline regions to prepare a highly tough piezoelectric elastomer. The effect of the composition and type of cross-linker on the crystalline structure and mechanical property of the PRX elastomer is investigated via X-ray diffraction, transmission electron microscopy, dynamic mechanical analysis, and tensile test. The piezoelectric properties of this elastomer and its possible application as a vibration sensor are confirmed through voltage generation and vocal cord sensing tests. Consequently, it has been confirmed for the first time that the PRX can induce piezoelectric properties, and that the PRX elastomer containing partially crystallized PRX bundles exhibits excellent mechanical toughness and piezo-electric effects.
저자 서지애1, 허준1, 김민석2, 이태곤1, 서소정1, 한승호3, 서지훈1
소속 1고려대, 2한국과학기술(연), 3한국전자기술(연)
키워드 polyrotaxane; piezoelectricity; elastomer; toughness; semicrystalline
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